He was a close friend of William Henry Fox Talbot, inventor of the calotype process, who sent Brewster early examples of his work. It was Brewster who suggested Talbot only patent his process in England, initiating the development of early photography in Scotland and eventually allowing for the formation of the first photographic society in the world, the Edinburgh Calotype Club, in 1843. Brewster was a prominent member of the club until its dissolution sometime in the mid-1850s; however, his interest in photography continued, and he was elected the first President of the Photographic Society of Scotland when it was founded in 1856.